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Activity 2.9 — Water of Crystallization

NCERT Activity 2.9: Heat blue copper sulphate crystals (CuSO₄·5H₂O). They turn white as water of crystallisation is driven off. Add water back — they turn blue again. The reaction is reversible.

How To Perform

1

Add CuSO₄·5H₂O Crystals

Blue crystals in a dry boiling tube.

2

Heat Gently

Water of crystallisation is driven off as steam.

3

Observe

Blue → white (anhydrous CuSO₄); water droplets on cooler walls.

4

Add Water Back

White powder → blue again (rehydration).

5

Conclude

CuSO₄·5H₂O ⇌ CuSO₄ + 5H₂O — reversible decomposition.

⚠️ Safety Notes

  • Hold the tube at an angle and point the mouth AWAY from your face.
  • Heat GENTLY — strong heating can decompose the salt further (CuSO₄ → CuO + SO₃).
  • Copper salts are toxic — wash hands after handling.