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Chromic Acid Test

Jones oxidation test: K₂Cr₂O₇/H₂SO₄ distinguishes oxidizable alcohols from 3° alcohols.

How It Works

1

Three Unknown Alcohols

Tubes A, B, C contain 1°, 2°, and 3° alcohols.

2

Add Chromic Acid

K₂Cr₂O₇/H₂SO₄ is orange. If the alcohol can be oxidized, it turns green.

3

Observe Color Change

Orange → Green = oxidizable (1° or 2°). No change = 3° alcohol.

Reaction Key

1° Alcohol:

Orange → Green (oxidized to aldehyde/carboxylic acid)

2° Alcohol:

Orange → Green (oxidized to ketone)

3° Alcohol:

No color change (cannot be oxidized)